Batteries
101
As
of: 26 January 2004
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What most people don't know about lead-acid batteries would
fill a book, and I'm not going to write one here. I've read the books and have seen about every condition printed in
them; but
this isn't a chemistry class. It's a short article to let you know what you
need to know about common battery problems. With these tidbits you'll know when a
battery is worth trying to revive and when it isn't. I'm going to keep
the article as simple as possible though some will obviously say, "Yeah, but he left this
or that out", and then expound about their knowledge about something they've read in a book
somewhere on some MG BBS somewhere on the internet.
That's okay. All I want to accomplish is to better educate some of you
guys and gals about how to determine yourself whether or not you have a good
battery in that old MG you just pulled out of grampa's barn or to allow you to
periodically check/maintain the battery you have in that MG you drive once a
month on a clear, dry Sunday afternoon.
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Most places test batteries with a load checker which puts a
heavy load on the battery with a big shunt or resistor. This quickly shows
the state of charge, but tells nothing about the condition of each individual
cell, nor if the battery is likely to hold a charge.
This is where a
hydrometer will tell the tale without charging the battery and running another
load check. There are several styles of battery hydrometers, but the one that
requires the least amount of electrolyte and can be used with even the
smallest lead acid batteries is the "pocket" type shown in the
photos. They usually cost $6.00 or less and are available at auto parts stores
and many discount stores.
The one pictured is a KD brand #2118 bought
from an auto parts something over 25 years ago and it works as good today as
it did right out of the blister pack. The glass is darkened by residue from
being used so many times you can hardly see the four balls, but they show up
good in actual use. Check the package and make sure it has clear instructions
for use before buying one. |
When using a small hydrometer like this
always fill the tube twice in each cell and take your reading on the second
fill (fill tube - dump back into cell - fill tube again & take
reading). The volume of the tube is so small that a high or low reading from one
cell can have a bearing on what the next one shows with just one filling.
Therefore, we use the first filling as a 'tube flush'. |
Never add water to a battery before checking with a hydrometer
unless it is so low on electrolyte that the tester can't pick it up. In that case,
top the cells off with water - preferably distilled water - charge the battery
fully, then check it. A hydrometer will find a defective cell even in a
battery that appears to be fully charged. When filling a battery use water
only, never electrolyte (acid), as this enriches the acid content to a point
it will begin dissolving the lead plates or eating away at the plate
separators. I never fill a cell higher than about 1/8 inch from the bottom of
the indicator ring. This helps to keep acid bearing moisture from gassing out
and corroding everything it touches.
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Batteries that are used
the least and not maintained by periodic charging fail much sooner
than those in normal service, but even this is not always reason to
replace them. When a lead-acid battery sits idle and is
allowed to slowly discharge the plates become sulfated. That is, the
sulfur in the sulfuric acid migrates to and saturates the lead
plates leaving the electrolyte too weak to support interaction
between the plates. There are mysterious battery restoring additives
on the market and what they do is attempt to desulfate the plates. I
say attempt to because sometimes they work and sometimes they don't,
but a good slow charge at 2 amps or less and checking each cell with
a hydrometer will tell the tale.
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The two batteries pictured here are prime examples of fully sulfated
ones being resurrected from the dead. They both sat idle for
about two years and tested deader than hammers any way I went at
it. Knowing the nature of idle batteries I set my charger at 2
amps, hooked up on one, and let 'er bump for 24 hours. At the
end of that time she showed a little promise of coming back from the
dead by having each cell float one ball in my hydrometer. I
continued to test it every 24 hours for a week and it came to 75%
charge on every cell so I took it off the charger and put the other
one on and went through the same drill again with the same
results. While the second battery was charging the first went
down a little, but it went down evenly on each cell, so I put it back
on the charger for another 24 hours. The result was a nearly
fully charged battery so I hit the other one with another 24 hours and
it came up a little more. In the end the Plus Start now has a
75% charge after sitting idle for a month and the Ever Start
holds nearly 100% for the same period of time. |
Why
did I mess with them at all? I was playing. Besides I may put one of
them back in service some time, either one should have at least a
year of good use left under favorable conditions. I normally get an
average of 6 years service from batteries, some more, some
less.
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Here is an example of a battery that would be good to go as is.
All the balls are floating in both pictures, but the fourth one is not
as high in photo 2. The rest of the cells floated all four high
but a variance this small is of no consequence even if only half of
them floated ball four. Even if some readings had ball four not
floating at all it's worth a slow charge to see if they even up.
This battery dropped to this stage from 100% charge in about 30
days of no use or charging. |
I acquired two batteries
like this one at once. One was in a 1981 VW Rabbit diesel
pickup I bought to rebuild, and the other was in a 1984 VW Jetta
turbo diesel I bought for parts and to upgrade the pickup.
Both vehicles had new batteries with little or no use and both had
sat idle for several weeks before I acquired them. Both
batteries were in a low state of charge and wouldn't kick the
engines over, however both had low but nearly even hydrometer
readings right down the line, and that told me they were probably
good ones. I slow charged each one overnight and they both
came to 100%. I had no use for them at the time but ended up
using one in my Mercedes 300D about a year later and it has
performed like new for about a year. After about 2 years I put
the other one in the pickup and It too performed like new.
The main point here is that both these marginal batteries were low,
but by testing them with a hydrometer before and after charging told
they were good to go without any doubts. Installing a used
battery with confidence is not possible without knowing the condition
of every cell.
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This is a battery that served well for seven and a half years in my
Scamp camper. It was put to use only a couple of weeks each year
but was treated well during it's life. While in use on the road,
it was either charged (1) by the towing vehicle, (2) when in an RV
parking spot and plugged into 110 volt current the converter in the
trailer charged it, and (3) when not in the Scamp it was properly
maintained. More than once when squatting somewhere other than
in an RV campground it operated the 12 volt lights all evening and two
12 volt fans all night with no perceptible loss of speed by the fans.
It was nearly 8 years old the last time I checked it, and it gave
the hydrometer readings you see in the pictures. One cell
floated none of the balls and the next floated all of them.
There was no need to check any further because two hydrometer
readings like these anywhere on any lead-acid battery
spells "The End". But, hey, 8 years of RV use?
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While a battery is in
service it is constantly being drawn down and charged up
again. During this process tiny flakes of material that make
up the plates and plate separators are being shed and settling to
the bottoms of the cells. Once this residue builds deep enough to
touch the bottoms of the lead cell plates it effectively short
circuits them and as that cell draws current from the rest in an
effort to remain equal it drags them down with it.
That's why some evening you may drive a perfectly starting vehicle
to the supermarket, do your shopping, and come out to a battery
that's "deader than
the chicken in your bag"
when you didn't leave anything turned on.
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It's important to properly maintain an idle battery, this is how I
do it. I place them in a convenient place with the plus post(s)
turned toward me so I never hook up one to the charger wrong.
About once a month I recharge them at a rate of 2 amperes per hour
until they are fully charged. This takes on the order of 15 to
30 minutes each and if the charge meter doesn't drop to zero in an
hour I run a hydrometer check on that battery to find out why.
Sometimes, like the Scamp battery they just reach the end of their
service life all at once, usually because of sediments in the
bottom. Some other reasons for sudden death, while in use, are
loose or corroded connections which is easy to repair, a broken cell
connector cell plates shaking out and falling down, (both of these
failures are quite rare), the battery is low on water, a failing or
failed alternator, and bad connections or a blown fuse in the
charging circuit.
Additional information about battery
maintenance and simple equipment to do it can be found in the
article "Charge
It, Please" on
this site.
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I hope this little piece
gives you a better insight into understanding lead-acid batteries, and
would like to dedicate it to the late Mr. Willis J. Pledger.
Mr. Pledger was a very wise but uncomplicated man and my mentor
in things mechanical. He was a battery rebuilding guru without
peer plying his skills with no fanfare, no fame, but always respected
by customers of his handiwork, and all who knew him.
John Dandy
(theAutoist
NOTE: John Weimer's new "nom de plume")
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